Petroleum Science >2011,??Issue 2:??224-228 DOI: https://doi.org/10.1007/s12182-011-0139-8
Synthesis, characterization and catalytic properties of Y-β zeolite composites Open?Access
文章信息
作者：Qin Bo,Zhang Xiwen,Zhang Zhizhi,Ling Fengxiang and Sun Wanfu
作者單位：
Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC, Fushun, Liaoning 113001, China;Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC, Fushun, Liaoning 113001, China;Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC, Fushun, Liaoning 113001, China;Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC, Fushun, Liaoning 113001, China;Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC, Fushun, Liaoning 113001, China
投稿時(shí)間：2010-09-01
引用方式：Qin, B., Zhang, X., Zhang, Z. et al. Pet. Sci. (2011) 8: 224. https://doi.org/10.1007/s12182-011-0139-8
文章摘要
Y-β zeolite composites were hydrothermally synthesized by using high silica Y zeolite as the precursor and characterized by XRD, N2 adsorption, SEM and IR spectra of pyridine. The result showed that the N2 adsorption-desorption isotherm of the zeolite composites had a distinct hysteresis loop, and the SEM result showed that the zeolite composites had a different morphology from Y, β and the corresponding physical zeolite mixture. The acid catalytic performance of the zeolite composite catalysts was investigated in the hydrocracking and hydroisomerization of n-octane, and the results showed that the composite materials exhibited an excellent hydrocracking activity and good hydroisomerization performance. The yield of i-C4 over the zeolite composite catalyst was 4.45% higher than that on the corresponding zeolite mixture in the n-octane hydrocracking process at 553 K. The isomerization ability of n-octane over the composite catalyst was 3.6 fold that of the corresponding mixture at 503 K.
關(guān)鍵詞
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Zeolite composites, synthesis, characterization, hydrocracking, hydroisomerization